International Chemical Safety Cards

TRI-ALLATE

ICSC: 0201

S-(2,3,3-Trichloroallyl) diisopropylthiocarbamate
S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate
C₁₀H₁₆Cl₃NOS / ((CH₃)₂CH)₂NCOSCH₂CCl=CCl₂
Molecular mass: 304.7

ICSC #    0201
CAS #     2303-17-5
RTECS # EZ8575000
UN #        2757
EC #         006-039-00-X

TYPES OF HAZARD/ EXPOSURE	ACUTE HAZARDS/ SYMPTOMS	PREVENTION	FIRST AID/ FIRE FIGHTING
FIRE	Combustible under specific conditions. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.		In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION

EXPOSURE		PREVENT DISPERSION OF DUST! PREVENT GENERATION OF MISTS! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!
•INHALATION		Local exhaust.	Fresh air, rest. Refer for medical attention.
•SKIN	Redness.	Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
•EYES	Redness.	Safety spectacles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION		Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. (Extra personal protection: A/P2 filter respirator for organic vapour and harmful dust).

Separated from strong bases, strong acids, food and feedstuffs. Dry. Keep in a well-ventilated room.

Do not transport with food and feedstuffs.
Xn symbol
R: 22
S: (2)
UN Hazard Class: 6.1
UN Packing Group: III

SEE IMPORTANT INFORMATION ON BACK

ICSC: 0201

Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 2001. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

TRI-ALLATE

ICSC: 0201

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PHYSICAL STATE; APPEARANCE:
CLEAR LIQUID OR COLOURLESS CRYSTALS

PHYSICAL DANGERS:

CHEMICAL DANGERS:
The substance decomposes on heating above 200°C or on burning producing toxic and corrosive gases including hydrogen chloride, nitrogen oxides and sulfur oxides.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration of airborne particles is reached on dispersing this substance.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the eyes and the skin.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:

PHYSICAL
PROPERTIES

Boiling point at 0.04 kPa: 117°C
Melting point: 29-30°C
Relative density (water = 1): 1.27
Solubility in water: none

Vapour pressure, Pa at 25°C: 0.016
Flash point: 90°C c.c.
Octanol/water partition coefficient as log Pow: 3.98 (calculated)

ENVIRONMENTAL
DATA

The substance is toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.

N O T E S

Technical Tri-allate is an oily amber liquid. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Ovadex BW, Dipthal and Far-Go are trade names.

Transport Emergency Card: TEC (R)-61G47c

ADDITIONAL INFORMATION

ICSC: 0201	TRI-ALLATE
(C) IPCS, CEC, 2001

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.